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Beilstein J. Org. Chem. 2011, 7, 1070–1074, doi:10.3762/bjoc.7.123
Graphical Abstract
Figure 1: Two examples of bioactive pseudopeptides bearing a CF2H group.
Scheme 1: Synthesis of difluoromethyl-containing pseudopeptides (4a–m) by Ugi reaction and desulfanylation.
Scheme 2: The Ugi reaction of aniline, benzaldehyde, (isocyanomethyl)benzene with acetic acid, difluoroacetic...
Scheme 3: Synthesis of 2,2-difluoro-2-(phenylthio)acetic acid (2).